I add Si last, right before i pH.
My tap is ~0.3ec. ~7.6pH.
My nutrient mix (including tap) pre Si is ~1.7ec. ~6.9pH.
Ive never had Si raise the pH to 8. Its normally only a few tenths.
So... while i see what your trying to avoid, i dont think the pH upswing caused by the Si is significant enough to cause fallout.
I guess either way will work, and again, i see what your trying to do, but id rather pH just once, rather than a possible two times..
(With stable tap water, i can estimate how much pH down im going to use anyway, negating the need for two pH adjustments.)
I think the issue is the Si:K ratio (as per analog, IIRC) and amount of product. Ex., 2.5 ml/gal of Pro-Tekt will not affect pH the same as 2.5 ml/gal SilicaBlast. I agree if the pH does not exceed ~7.5 it's less of a concern. However, even before I used Si I would pH adjust water before adding ferts, to try and keep them as soluble as possible.
When adding D.M. Silica at 7.5 ml/gal the water will reach pH > 8, so in that case pH adjusting seems like time worth spending.
I chalk up my multiple pHing and what I wrote about Si to my anal-retentive nature.