SRGB
Member
bobblehead:
[#252]
I don't know about the exchange of electrical charges...
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[#254]
Its even more difficult to balance coco's CEC with slow release ferts. I'm sure it can be done, but I'm not trying to experiment.
Hi, bobblehead.
In general, from what we could gather, it appears plants` roots (at least to the extent that humans have an appreciable understanding of the process) absorb `nutrients`, positive (cations) or negative (anions), that is, `electrical charges` (ions) in a solution, and correspondingly release ions (of an opposite charge) into the surrounding media (soil, moist air, or water culture).
The process could be described as `cation exchange`, and if measuring a medium for its ability to facilitate this exchange process, the process could be described as `cation exchange capacity`, or, the `capacity` (total amount of cations capable in a given medium) - to facilitate conduction of electrical charges between its physical composition or `solution` and the plants` roots.
Example cations (positively `+` charged):
Hydrogen (H+), postassium (K+), calcium (Ca++), magnesium (Mg++), ammonium (NH4+), iron (Fe++), manganese (Mn++), zinc (Zn++). Absorbed on the negatively charged collidial surfaces of the media.
Examplee anions (negatively `-` charged):
Nitrates (NO3-), phosphates (HPO4--), sulphates (SO4--), chlorides (Cl-). Predominantly found in nutrient `solution`, absorbed when the solution flows over the roots, and can possibly be washed out of the medium with overwatering.
For example, with the uptake of one (1) calcium (Ca++) ion the root releases two hydrogen ions (H+). Removal of anions, i.e.g., nitrates and phospahates absorbed by plant roots releases hydroxyl groups (OH-) and bicarbonates (HCO3-) in to the surrounding medium.
The above process, in brief, might tend to affect the pH of the surrounding medium. Removal of cations from the medium might tend to make the pH of the medium more acidic, while removal, or `exchange` of anions might tend to make the medium more alkaline, which might lend to futher interpretations of `EC`, or the `electrical conductivity` of a given solution - and the corresponding pH at a given EC.
Additionally, certain organisms have appeared to have developed a symbiotic relationship with plant roots, which appears to facilitate nutrition for both the organisms and the plants. See below at Plant Acquisition of Nutrients: Symbioses with Soil-based Microorganisms. Though the article does not address the types of substrate in which those organisms can thrive in; e.g., inert rocks, soil, coco coir, peat, etc. If their nutrition is primarily derived from plant roots, the medium might only need to permit persistent proximity to the roots, whether soil or rocks, as the population would not necessarily derive its nutrition from the soil nor rocks, but the roots themselves.
We will not delve into the further corresponding topic of solubility of specific elements or compounds in a solution at a given solution pH, yet it might be equally revealing to examine which elements are chemically soluble at which pH ranges.
Thes following articles (excerpts) might assist in more clearly defining some common terms, chemical and electrical properties, and corresponding processes:
The pH Factor in Hydroponics by Dr. Lynette Morgan
Definition of pH
The scientific definition of pH is `the negative logarithm of the hydrogen ion
concentration,` but in everyday terms the pH is a scale for measuring the acidity or alkalinity of a solution. Pure water, which has the chemical formula H20, means it has one hydrogen (H+) and one hydroxyl ion (OH-) - perhaps better expressed as H-OH. Because water has one hydrogen and one hydroxyl group, which split up or `dissociate` into electrically charged particles called ions, it`s balanced with an acid and alkaline and is therefore neutral:
H2O --> H-OH --> H+ + OH-
The positively charged particle (H+) is the hydrogen ion, and the negative particle (OH-) is the hydroxyl ion.
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The most common method of buffering a nutrient solution is by adding small amounts of the ammonium form of nitrogen (NH4+) in the original formulation. Ammonium nitrogen in time tends to reduce pH, whereas nitrate (NO3-) increases it. If nitrogen is in the ammonium form (NH4+), hydrogen ions are discharged through the plants roots resulting in a lower pH, and if it`s in the nitrate form (NO3-), hydroxyl ions (OH-) are discharged and the pH in the root zone is increased. This provides a useful method of controlling pH swings, but not morethan 20% of the total nitrogen should be in the ammonium form.
Electrical Conductivity in Hydroponics by Dr. Lynette Morgan
Conductivity and Nutrient Chemistry
Hydroponic fertilizers are very soluble compunds that possess ionic bonds. We commonly call these hydroponic fertilizers `nutrient salts` becuase they bond between two electrostatic attraction between positively and negatively charged ions. When these ionically bonded compounds are added to water to make up a nutrient solution, they break up (dissociate) into their differently charged ions. This process causes the water, which is normally unable to conduct a charge, to become a conductor of electricity. The amount of electricity depends on the type of ions (for example, which salt they came from), the concentration of the ions in solution, and the temperature of the solution.
Fundamentals of Soil Cation Exchange Capacity (CEC) AY-238 AY-238 Soils (Fertility)
extension.purdue .edu/extmedia/ay/ay-238.html
(In pertinent part)
Forms of Nutrient Elements in Soils
Elements having an electrical charge are called ions. Positively-charged ions are cations; negatively-charged ones are anions.
The most common soil cations (including their chemical symbol and charge) are: calcium (Ca++), magnesium (Mg++), potassium (K+), ammonium (NH4+), hydrogen (H+) and sodium (Na+). Notice that some cations have more than one positive charge.
Common soil anions (with their symbol and charge) include: chlorine (Cl-), nitrate (NO3-), sulfate (SO4--) and phosphate (PO43-). Note also that anions can have more than one negative charge and may be combinations of elements with oxygen.
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Defining Cation Exchange Capacity
Cations held on the clay and organic matter particles in soils can be replaced by other cations; thus, they are exchangeable. For instance, potassium can be replaced by cations such as calcium or hydrogen, and vice versa.
The total number of cations a soil can hold--or its total negative charge--is the soil's cation exchange capacity. The higher the CEC, the higher the negative charge and the more cations that can be held.
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Cation exchange capacity is usually measured in soil testing labs by one of two methods. The direct method is to replace the normal mixture of cations on the exchange sites with a single cation such as ammonium (NH4+), to replace that exchangeable NH4+ with another cation, and then to measure the amount of NH4+ exchanged (which was how much the soil had held).
More commonly. the soil testing labs estimate CEC by summing the calcium, magnesium and potassium measured in the soil testing procedure with an estimate of exchangeable hydrogen obtained from the buffer pH. Generally, CEC values arrived at by this summation method will be slightly lower than those obtained by direct measures.
ROOTS, GROWTH AND NUTRIENT UPTAKE
Dept. of Agronomy publication # AGRY-95-08 (Rev. May-95)
The nutrient uptake process.
Movement of nutrients to roots. For nutrient uptake to occur, the individual nutrient ion most be in position adjacent to the root. This process of positioning occurs through three basic ways.
The root can "bump into" the ion as it grows through the soil. This mechanism is called root interception. Work by Barber estimates that perhaps one percent of the nutrients in a corn plant come from the root interception process.
The soluble fraction of nutrients which are present in soil solution (water) and are not held on the soil fractions flow to the root as water is taken up. This process is called mass flow. Nutrients such as nitrate-N, calcium, and sulfur are normally supplied by mass flow.
Morgan, J. B. & Connolly, E. L. (2013) Plant-Soil Interactions: Nutrient Uptake. Nature Education Knowledge 4(8):2
nature .com/scitable/knowledge/library/plant-soil-interactions-nutrient-uptake-105289112
Plant Acquisition of Nutrients: Symbioses with Soil-based Microorganisms
Nitrogen and phosphorus are among the elements considered most limiting to plant growth and productivity because they are often present in small quantities locally or are present in a form that cannot be used by the plant. As a result, the evolution of many plant species has included the development of mutually beneficial symbiotic relationships with soil-borne microorganisms. In these relationships, both the host plant and the microorganism symbiont derive valuable resources that they need for their own productivity and survival as a result of the association.
Nitrogen Fixation. Despite the fact that nitrogen is the most abundant gaseous element in the atmosphere, plants are unable to utilize the element in this form (N2) and may experience nitrogen deficiency in some soils that have low nitrogen content. Since nitrogen is a primary component of both proteins and nucleic acids, nitrogen deficiency imposes significant limitations to plant productivity. In an agricultural setting, nitrogen deficiency can be combated by the addition of nitrogen-rich fertilizers to increase the availability of nutrients and thereby increase crop yield. However, this can be a dangerous practice since excess nutrients generally end up in ground water, leading to eutrophication and subsequent oxygen deprivation of connected aquatic ecosystems.
Plants are able to directly acquire nitrate and ammonium from the soil. However, when these nitrogen sources are not available, certain species of plants from the family Fabaceae (legumes) initiate symbiotic relationships with a group of nitrogen fixing bacteria called Rhizobia. These interactions are relatively specific and require that the host plant and the microbe recognize each other using chemical signals. The interaction begins when the plant releases compounds called flavanoids into the soil that attract the bacteria to the root (Figure 4). In response, the bacteria release compounds called Nod Factors (NF) that cause local changes in the structure of the root and root hairs. Specifically, the root hair curls sharply to envelop the bacteria in a small pocket. The plant cell wall is broken down and the plant cell membrane invaginates and forms a tunnel called an infection thread that grows to the cells of the root cortex. The bacteria become wrapped in a plant derived membrane as they differentiate into structures called bacteroids. These structures are allowed to enter the cytoplasm of cortical cells where they convert atmospheric nitrogen to ammonia, a form that can be used by the plants. In return, the bacteroids receive photosynthetically derived carbohydrates to use for energy production (reviewed by Limpens & Bisseling, 2003; Ferguson et al. 2010).
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Mycorrhizal interactions with plants.
In addition to symbiotic relationships with bacteria, plants can participate in symbiotic associations with fungal organisms as well. Current estimates of the frequency of plant-mycorrhizal associations suggest that around 80% of all plants establish some type of mycorrhizal symbiosis, and many studies indicate that these relationships are millions of years old (Karandashov & Bucher, 2005; Vance, 2001). There are several classes of mycorrhiza, differing in structural morphology, the method of colonizing plant tissue, and the host plants colonized. However, there are two main classes that are generally regarded as the most common and therefore, the most ecologically significant. The endomycorrhizae are those fungi that establish associations with host plants by penetrating the cell wall of cortical cells in the plant roots. By contrast, ectomycorrizae develop a vast hyphae network between cortical cells but do not actually penetrate the cells.
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Summary
Although plants are non-motile and often face nutrient shortages in their environment, they utilize a plethora of sophisticated mechanisms in an attempt to acquire sufficient amounts of the macro- and micronutrients required for proper growth, development and reproduction. These mechanisms include changes in the developmental program and root structure to better "mine" the soil for limiting nutrients, induction of high affinity transport systems and the establishment of symbioses and associations that facilitate nutrient uptake. Together, these mechanisms allow plants to maximize their nutrient acquisition abilities while protecting against the accumulation of excess nutrients, which can be toxic to the plant. It is clear that the ability of plants to utilize such mechanisms exerts significant influence over crop yields as well as plant community structure, soil ecology, ecosystem health, and biodiversity.
We hope that this post might be helpful.
Kind regards,
/SRGB/
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