You need to let it sit for 3hrs for PHing it then. PH raises only under a few conditions. During heavy aeration (co2 bubbling thru it), while theres a plant growing directly in it (DWC) or right after mixing it when all your ions are still dancing.
Anyways my problem was solved when I started using epsom salt. I am still using tap water.
It isn't heavily aerated, and there isn't a plant growing in it. If you could be bothered to take the time to read my post, the water is sitting in a bucket. Does epsom salt act as a buffer?