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I'm sure it can be done, however a caveat. Peppers, at least all that I've grown to date, are calcium hogs. Coco latches onto both Ca and Mg, so you'll need to be extra diligent AND extra prepared. Have separate Ca and Mg supplements, and be certain to get that coco properly pre-charged, especially with PLENTY of Ca/Mg (use your supplement of choice, I use a separate Ca product + MgSO4).
I currently have a tiny habanero plant and wondered where to get these nutrients you guys speak of. I'm not looking to spend an excessive amount as I'm not even sure that I'll eat them-I'd prefer to just give them to friends.