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i agree with the combustion part creating a lot of carbon monoxide, along with other bi products.. maybe im wrong. natural gas also has a bi product of carbon monoxide and what not, but had been time tested to work, along with propane.
bottled co2 is a pain in the rump and may be out of the question for your room size. but its effective
there might be a way to channel off the co2 like the blue ox gen i think it was called. co2 sinks but i wouldnt waste my time with a wood source. if you manage to do it without introducing alot of contaminates let me know.if this could work i am moving back to maine free co2 with your heating. lol
If the wood is combusting completely, little or no CO is produced. So all you need is a tank of O2 and a properly designed burner. Which of course is way more trouble than just a tank of CO2.